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  1. Abstract

    The present-day deep ocean global meridional overturning circulation is dominated by the Atlantic meridional overturning circulation (AMOC), with dense water sinking in the high-latitude North Atlantic Ocean. In contrast, deep-water formation in the subarctic North Pacific is inhibited by a strong upper-ocean halocline, which prevents the development of an analogous Pacific meridional overturning circulation (PMOC). Nevertheless, paleoclimate evidence suggests that a PMOC with deep-water formation in the North Pacific was active, for instance, during the warm Pliocene epoch and possibly during the most recent deglaciation. In the present study, we describe a spontaneous activation of the PMOC in a multimillennial abrupt 4 × CO2experiment using one of the configurations of the Community Earth System Model (CESM1). Soon after the imposed CO2increase, the model’s AMOC collapses and remains in a weakened state for several thousand years. The PMOC emerges after some 2500 years of integration, persists for about 1000 years, reaching nearly 10 Sv (1 Sv ≡ 106m3s−1), but eventually declines to about 5 Sv. The PMOC decline follows the AMOC recovery in the model, consistent with an Atlantic–Pacific interbasin seesaw. The PMOC activation relies on two factors: (i) gradual warming and freshening of the North Pacific deep ocean, which reduces ocean vertical stratification on millennial time scales, and (ii) upper-ocean salinity increase in the subarctic North Pacific over several centuries, followed by a rapid erosion of the pycnocline and activation of deep-water formation. Ultimately, our results provide insights on the characteristics of global ocean overturning in warm climates.

     
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  2. Abstract

    The evolution of tropical sea surface temperatures (SSTs) in response to greenhouse warming is of great societal and scientific interest. Most state‐of‐the‐art climate models predict a mean “El Niño‐like” warming pattern by century‐end, characterized by greater warming over the Pacific cold tongue compared to the western warm pool. However, it is unclear which proposed mechanism dominates in this response. Here, we present partially coupled abrupt CO2doubling experiments in which surface wind stress and shortwave heating are overridden to values from a control simulation. Contrary to previous studies, we find that experiments with overriding of surface wind stress exhibit only 58% of the full reduction in east‐west SST contrast. When both surface wind stress and shortwave flux are overridden, only 34% of the full reduction remains, controlled by spatially‐varying evaporative cooling. These results underscore the importance of Bjerknes and shortwave feedbacks in the tropical Pacific SST response to global warming.

     
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  3. Abstract CO 2 -forced surface warming in general circulation models (GCMs) is initially polar amplified in the Arctic but not in the Antarctic—a largely hemispherically antisymmetric signal. Nevertheless, we show in CESM1 and 11 LongRunMIP GCMs that the hemispherically symmetric component of global-mean-normalized, zonal-mean warming ( ) under 4 × CO 2 changes weakly or becomes modestly more polar amplified from the first decade to near-equilibrium. Conversely, the antisymmetric warming component ( ) weakens with time in all models, modestly in some including FAMOUS, but effectively vanishing in others including CESM1. We explore mechanisms underlying the robust behavior with a diffusive moist energy balance model (MEBM), which given radiative feedback parameter ( λ ) and ocean heat uptake ( ) fields diagnosed from CESM1 adequately reproduces the CESM1 and fields. In further MEBM simulations perturbing λ and , is sensitive to their symmetric components only, and more to that of λ . A three-box, two-time-scale model fitted to FAMOUS and CESM1 reveals a curiously short Antarctic fast-response time scale in FAMOUS. In additional CESM1 simulations spanning a broader range of forcings, changes modestly across 2–16 × CO 2 , and in a Pliocene-like simulation is more polar amplified but likewise approximately time invariant. Determining the real-world relevance of these behaviors—which imply that a surprising amount of information about near-equilibrium polar amplification emerges within decades—merits further study. 
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  4. Molecular doping can increase the conductivity of organic semiconductors and plays an increasingly important role in emerging and established plastic electronics applications. 4-(1,3-Dimethyl-2,3-dihydro-1 H -benzimidazol-2-yl)- N , N -dimethylaniline (N-DMBI-H) and tris(pentafluorophenyl)borane (BCF) are established n- and p-dopants, respectively, but neither functions as a simple one-electron redox agent. Molecular hydrogen has been suggested to be a byproduct in several proposed mechanisms for doping using both N-DMBI-H and BCF. In this paper we show for the first time the direct detection of molecular hydrogen in the uncatalysed doping of a variety of polymeric and molecular semiconductors using these dopants. Our results provide insight into the doping mechanism, providing information complementary to that obtained from more commonly applied methods such as optical, electron spin resonance, and electrical measurements. 
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  5. Abstract

    The role of precipitation efficiency (PE)—the fraction of column‐integrated condensate that reaches the surface as rain—in the global temperature response to CO2rise is yet to be quantified. Here we employ 36 limited‐domain cloud resolving models (CRMs) from the Radiative‐Convective Equilibrium Model Intercomparison Project and find that they strongly imply higher PE at warmer temperatures. We then analyze 35 general circulation models (GCMs) from the Coupled Model Intercomparison Project Phase 6 and find that increasing PE is associated with tropical circulation slowdown and greater eastern equatorial Pacific warming. These changes trigger pan‐tropical positive cloud feedback through stratiform anvil cloud reduction and stratocumulus suppression, resulting in higher Effective Climate Sensitivity (ECS). We find that in 24 of 35 GCMs matching the CRMs in simulating increasing PE with greenhouse warming, mean ECS is 1 K higher than in PE‐decreasing GCMs. Thus, further constraining PE sensitivity to temperature could reduce uncertainty over future climate projections.

     
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  6. null (Ed.)
    Abstract This study compares the impacts of Arctic sea ice decline on the Atlantic Meridional Overturning Circulation (AMOC) in two configurations of the Community Earth System Model (CESM) with different horizontal resolution. In a suite of model experiments we impose radiative imbalance at the ice surface, replicating a loss of sea ice cover comparable to the observed during 1979-2014, and find dramatic differences in the AMOC response between the two models. In the lower-resolution configuration, the AMOC weakens by about one third over the first 100 years, approaching a new quasi-equilibrium. By contrast, in the higher-resolution configuration, the AMOC weakens by ~10% during the first 20-30 years followed by a full recovery driven by invigorated deep water formation in the Labrador Sea and adjacent regions. We investigate these differences using a diagnostic AMOC stability indicator, which reflects the AMOC freshwater transport in and out of the basin and hence the strength of the basin-scale salt-advection feedback. This indicator suggests that the AMOC in the lower-resolution model is less stable and more sensitive to surface perturbations, as confirmed by hosing experiments mimicking Arctic freshening due to sea ice decline. Differences between the models’ mean states, including the Atlantic mean surface freshwater fluxes, control the differences in AMOC stability. Our results demonstrate that the AMOC stability indicator is indeed useful for evaluating AMOC sensitivity to perturbations. Finally, we emphasize that, despite the differences in the long-term adjustment, both models simulate a multi-decadal AMOC weakening caused by Arctic sea ice decline, relevant to climate change. 
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